Hoare Logic is a formal system used to reason about the correctness of computer programs through assertions and preconditions. It utilizes triples, typically represented as {P} C {Q}, where P is the precondition, C is the command or program segment, and Q is the postcondition. This method allows programmers and theorists to prove that if the precondition holds before executing a program, then the postcondition will hold after execution, which is essential in applications involving formal verification in computer science and AI.