Non-adiabatic transitions refer to the processes where a quantum system transitions between different energy states without maintaining a constant energy level throughout the process. This occurs when external conditions change rapidly or when interactions with other systems induce transitions, allowing the system to exchange energy with its environment. In the context of Rydberg atoms and highly excited states, non-adiabatic transitions are critical in understanding the dynamics of these systems as they can significantly affect their stability and interaction properties.
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