The Zeroth Law of Thermodynamics states that if two systems are each in thermal equilibrium with a third system, then they are in thermal equilibrium with each other. This fundamental principle helps establish a baseline for temperature measurement, as it implies that temperature is a measurable property that can be used to determine the thermal state of systems. The Zeroth Law is crucial for understanding how heat transfer operates between different entities and lays the groundwork for the other laws of thermodynamics.
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