Fiveable
🧲AP Physics 2
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FRQ 1 – Mathematical Routines
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Unit 9: Thermodynamics
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Practice FRQ 1 of 12
1. A rigid, sealed container of fixed volume V=0.020 m3V = 0.020\ \text{m}^3V=0.020 m3 holds n=0.80 moln = 0.80\ \text{mol}n=0.80 mol of an ideal monatomic gas. The gas is initially in thermal equilibrium at temperature T1=300 KT_1 = 300\ \text{K}T1​=300 K and pressure P1P_1P1​. The container is placed in thermal contact with a large thermal reservoir whose temperature can be changed, as shown in Figure 1. The container walls are thin enough that the gas can exchange energy with the reservoir, but the container volume remains constant.

Figure 1. Rigid sealed container of fixed volume in thermal contact with an adjustable-temperature reservoir (constant-volume heating).

Black-and-white physics setup diagram with two main objects: a rigid gas container on the left and a large thermal reservoir block on the right, drawn so they touch along a shared vertical contact surface.

Overall layout:
- The rigid container occupies the left half of the figure; the thermal reservoir occupies the right half.
- The container’s right wall is drawn flush against (touching) the reservoir’s left face to indicate thermal contact.

Rigid sealed container (left):
- Draw a tall rectangle representing the container, with thick, straight walls to emphasize rigidity.
- Inside the rectangle, place 10–14 small solid dots (gas particles) scattered throughout the interior (not touching each other; some may be near walls but not overlapping walls).
- Centered inside the container, include the text label: "ideal monatomic gas".
- Near the top edge of the container (inside or just above it), place a clear label: "V = 0.020 m^3".
- Near the lower-left of the container, add two stacked initial-condition labels, both clearly associated with the gas (not the reservoir):
  - "n = 0.80 mol"
  - "State 1: T1 = 300 K, P1"
  The text "P1" must appear exactly as written (no numeric value).
- Explicitly indicate sealed/closed: draw the container with no openings, no valves, and no piston. Add a small label just above the container: "rigid, sealed".

Thermal reservoir (right):
- Draw a much larger rectangular block than the container (at least 1.5 times the container’s height and width), occupying most of the right half of the figure.
- On the front face of the reservoir block, place the label "thermal reservoir" near the top-center.
- Directly below that, place a large label "T_res" (exact text with subscript styling if possible; otherwise "T_res").
- Add a thermometer icon on the reservoir face: a vertical thin tube with a round bulb at the bottom, positioned on the upper-right quadrant of the reservoir block.
- To emphasize that the reservoir temperature can be changed, add a small double-headed vertical arrow next to the thermometer with the text "adjustable" next to the arrow.

Thermal contact cue:
- At the interface between container and reservoir, add short, evenly spaced hatch marks or small zig-zag heat-transfer marks centered on the touching boundary to indicate thermal energy exchange.
- Do NOT draw any moving boundary, piston, or volume-change mechanism anywhere in the figure.

Line/label clarity:
- All labels are horizontal, non-italic block text except variables (V, n, T1, P1, T_res) which may be italicized in standard physics style.
- No axes, no graph, no grid.

Figure 2. Particle-speed comparison between State 1 (300 K) and State 2 (450 K) at constant volume.

Two-panel vector diagram arranged side-by-side with identical containers, labeled state information, gas particles, and sample velocity arrows that students compare by drawing arrow lengths.

Panel layout:
- Left panel title at the top: "State 1".
- Right panel title at the top: "State 2".
- Directly under each title, include the temperature label in the same font size:
  - Under State 1: "T1 = 300 K"
  - Under State 2: "T2 = 450 K"
- The two panels must be the same size and aligned horizontally with a clear gap between them.

Container in each panel:
- Draw an identical rectangle container in each panel, centered within the panel.
- The rectangle has thin walls and no openings.

Gas particles (dots) in each panel:
- In each container, draw exactly 12 solid circular dots.
- Use the same dot positions in both panels (a one-to-one spatial match) to avoid implying density change. Distribute them across the interior: some near corners, some near center, none overlapping walls.

Velocity arrows (sample) in each panel:
- In each container, select exactly 4 of the 12 particles and draw a velocity arrow originating at the center of each selected dot.
- The 4 arrows in a given panel point in four different directions to indicate random motion:
  - one arrow pointing up-right (northeast),
  - one arrow pointing up-left (northwest),
  - one arrow pointing down-right (southeast),
  - one arrow pointing down-left (southwest).
- In State 1 panel, all four arrows have exactly the same length (this is the reference arrow length for student comparison).
- In State 2 panel, the arrows are present in the same directions and attached to the same corresponding dots as in State 1, but their lengths are left for the student to modify; provide faint placeholder arrows (light gray, thin) of the SAME length as the State 1 arrows so students can clearly lengthen or shorten them.

Student response cue:
- In the State 2 panel only, add a small instruction text just below the container: "Draw longer/shorter arrows to show typical speed".
- Do NOT include any numeric speed values.

Consistency constraints:
- The containers in both panels are identical size and shape.
- The number of dots (12) and which dots carry arrows (4) are identical in both panels.
- Only arrow length is intended to differ between State 1 and State 2.

Figure 3. Comparing average force exerted on a container wall at State 1 vs State 2.

A single diagram showing a vertical container wall segment with gas particles nearby, plus two separate boxed response areas labeled by state where students draw a force-magnitude arrow.

Overall layout:
- The left side of the figure shows the wall-collision sketch.
- The right side of the figure shows two stacked response boxes (top box for State 1, bottom box for State 2).

Wall and particles (left side):
- Draw a thick vertical line representing a container wall segment, placed on the left third of the figure.
- To the immediate right of this wall line (inside the gas), draw exactly 6 solid dots (gas particles) at varying distances from the wall.
- For 3 of the 6 particles (choose the ones closest to the wall), draw short straight motion arrows pointing directly toward the wall (leftward arrows), indicating impending collisions.
- For 2 of the particles that are very near the wall, draw short straight motion arrows pointing directly away from the wall (rightward arrows), indicating particles just after collision.
- Leave the 6th particle with no arrow (to avoid clutter).
- Above the wall/particle sketch, add a small label: "container wall" with a thin leader line pointing to the thick vertical wall line.

Response boxes (right side):
- Draw two identical empty rectangles (answer boxes) stacked vertically with a small gap between them.
- The top box is labeled "State 1" centered above the top box.
- The bottom box is labeled "State 2" centered above the bottom box.
- Inside each box, include a faint, light-gray horizontal guideline arrow template starting near the left interior edge and pointing to the right, with an arrowhead on the right end. This template indicates the direction students should draw their force-magnitude arrow.
- Next to each state label (either to the right of the label or inside the top-left corner of the box), include the temperature text:
  - For State 1: "T1 = 300 K"
  - For State 2: "T2 = 450 K"
- Add a short instruction centered between the wall sketch and the boxes: "In each box, draw an arrow whose LENGTH represents average force on the wall".

Clarity constraints:
- The only intended difference between State 1 and State 2 is arrow length in the response boxes.
- Do NOT include any numeric force values.
- Keep the collision sketch neutral: it is illustrative and not different between states.
A.
i. The reservoir temperature is increased until the gas reaches a new equilibrium temperature T2=450 KT_2 = 450\ \text{K}T2​=450 K. Complete the following tasks in Figures 2 and 3.
• Indicate in Figure 2 whether the typical particle speed at State 2 is greater than, less than, or the same as at State 1 by drawing longer, shorter, or equal-length velocity arrows.
• Indicate in Figure 3 whether the average force exerted by the gas on the container wall at State 2 is greater than, less than, or the same as at State 1 by drawing a longer, shorter, or equal-length arrow in each box.
ii. Assume the gas can be modeled as an ideal monatomic gas. Derive an expression for the change in internal energy ΔU=U2−U1\Delta U = U_2 - U_1ΔU=U2​−U1​ in terms of nnn, T1T_1T1​, and T2T_2T2​. Begin your derivation by writing a fundamental physics principle or an equation from the reference information.
B. Indicate whether the heat transferred to the gas is positive, negative, or zero.
______ Positive
______ Negative
______ Zero
Justify your answer.

Figure 4. Pressure–volume diagram for heating at constant volume V = 0.020 m^3 from State 1 to State 2.

A clean P–V graph with fully specified axis labels, numeric tick labels, and a constant-volume process shown as a vertical line at V = 0.020 m^3 with two labeled state points.

Axes:
- Horizontal axis labeled "V (m^3)" with an arrow at the far right end.
- Vertical axis labeled "P (Pa)" with an arrow at the top end.
- The origin at the bottom-left corner is labeled "0" on both axes.

Horizontal axis (volume) numeric scale:
- Show tick marks and printed tick labels at: 0.00, 0.01, 0.02, 0.03, 0.04.
- The tick label "0.02" must be present and aligned under its tick mark.

Vertical axis (pressure) numeric scale:
- Show tick marks and printed tick labels at: 0, 5.0×10^4, 1.0×10^5, 1.5×10^5, 2.0×10^5.
- Use scientific notation exactly as shown with the multiplication sign and power of ten formatting (acceptable as "5.0x10^4" if the renderer cannot typeset × and superscripts).

Constant-volume process line:
- Draw a solid vertical line exactly above the volume tick labeled 0.02 (so the line passes through V = 0.020 m^3).
- Place two filled circular markers on this vertical line:
  - Point "1" is the lower marker, located slightly above the tick labeled 1.0×10^5.
  - Point "2" is the upper marker, located exactly halfway between the ticks labeled 1.5×10^5 and 2.0×10^5.
- Label the lower point with the text "1" placed just to the left of the marker.
- Label the upper point with the text "2" placed just to the left of the marker.

Direction of process:
- Draw a single arrow on the vertical line pointing upward from point 1 toward point 2.
- Near the arrow, add the text "constant V".

No extra elements:
- No curve, no other lines, no shading, no grid.






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