3. In an investigation of the thermodynamic behavior of a gas, a student uses a fixed amount of dry air confined in a cylinder with a movable piston. The student will design an experiment to determine a thermodynamic property of the gas and then analyze a second set of data to determine that property from a graph.
Figure 1. Cylinder-piston apparatus for gas measurement

Figure 2. Cartesian grid for moles determination

Describe a procedure for collecting data that would allow the student to determine the number of moles n of gas in the cylinder. In your description, include the measurements to be made. Include any steps necessary to reduce experimental uncertainty.
Describe how the collected data could be analyzed to determine n. Include references to appropriate equations and to relationships between measured and known quantities.
P (kPa) | V (x10^-4 m^3) |
|---|---|
120 | 6.24 |
140 | 5.35 |
160 | 4.68 |
180 | 4.16 |
200 | 3.74 |
In a second experiment, the student places the cylinder in the 300 K water bath and waits until the gas reaches thermal equilibrium at T = 300 K for each trial. The student then changes the external load on the piston and records the equilibrium pressure P and volume V of the gas. Table 1 shows the collected data.
Indicate two quantities, either measured quantities from Table 1 or additional calculated quantities, that could be graphed to produce a straight line that could be used to determine n.
Vertical axis: Horizontal axis:
On the grid provided, create a graph of the quantities indicated in part C(i) that can be used to determine n.
Use Table 2 to record the data points or calculated quantities that you will plot.
Clearly label the axes, including units as appropriate.
Plot the points you recorded in Table 2.
Draw a best-fit line for the data graphed in part C(ii).
Using the best-fit line that you drew in part C(iii), calculate an experimental value for the number of moles n of the gas. Use R = 8.31 J/(mol·K) and T = 300 K.