2. A sample of monatomic ideal gas is sealed in a vertical cylinder by a movable piston of mass and cross-sectional area , as shown in Figure 1. The piston moves with negligible friction and forms an airtight seal. The gas is in thermal contact with a large thermal reservoir at temperature through the cylinder walls. The pressure of the air above the piston is . At the instant shown, the piston is at rest and the gas occupies volume .
Figure dot. Force diagram (free-body diagram template for the piston).
Figure 1. Vertical cylinder with monatomic ideal gas sealed by a movable piston; thermal contact with a 300 K reservoir; atmosphere above piston at 1.01×10⁵ Pa; initial gas volume 3.60×10⁻³ m³.
On the dot shown in the force diagram, representing the piston, draw and label the forces that are exerted on the piston. Each force must be represented by a distinct arrow starting on, and pointing away from, the dot.
Derive an expression for the internal energy of the gas at the instant shown in terms of , , , , and physical constants, as appropriate. Begin your derivation by writing a fundamental physics principle or an equation from the reference information.
Figure 2. Blank P–V axes for the thermodynamic process sketch.
On the axes provided in Figure 2, sketch the expected relationship between the pressure and volume of the gas for the thermodynamic process that the gas undergoes while the mass is being added. Draw an arrow on your sketch to represent the direction of the thermodynamic process. An additional mass is slowly placed on top of the piston. The system remains in thermal contact with the reservoir at , and the piston comes to rest at a new equilibrium volume .
Indicate whether the average translational kinetic energy per gas molecule is greater during the final equilibrium state at than it was in the initial equilibrium state at . With the added mass still on the piston, the reservoir temperature is increased to and held constant until the gas reaches thermal equilibrium. During this heating process, the piston rises and the gas expands from volume to a final volume . Assume the pressure exerted by the gas on the piston equals the external pressure at all times.
Given values:
Greater at
Less at
The same at
Briefly justify your answer by relating temperature to atomic motion and by referencing at least one feature of your representations in parts A, B, or C.
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