2. A sample of a monatomic ideal gas is sealed in a vertical cylinder by a frictionless, movable piston of mass and cross-sectional area , as shown in Figure 1. The pressure of the air above the piston is constant at . The cylinder is surrounded by a large thermal reservoir initially at a constant temperature , and the cylinder wall is thermally conducting. At the instant shown, the gas is in thermal equilibrium with the reservoir, the piston is at rest, and the gas occupies volume .
Figure dot. Force diagram (piston).
Figure 1. Vertical cylinder with monatomic ideal gas under a frictionless movable piston in thermal contact with a reservoir at T₀.
On the dot shown in the force diagram, representing the piston, draw and label the forces that are exerted on the piston. Each force must be represented by a distinct arrow starting on, and pointing away from, the dot.
Derive an expression for the internal energy of the gas in terms of , , , , and physical constants, as appropriate. Begin your derivation by writing a fundamental physics principle or an equation from the reference information.
Figure 2. Axes for a P–V diagram.
On the axes provided in Figure 2, sketch the expected relationship between the pressure and volume of the gas for the thermodynamic process that the gas undergoes while the block is being added. Draw an arrow on your sketch to represent the direction of the thermodynamic process. A metal block of mass is gently placed on top of the piston. The block is added slowly enough that the gas remains in thermal equilibrium with the reservoir at throughout the compression, and the piston comes to rest at a new equilibrium position.
Indicate whether the entropy change of the gas, , from the moment the reservoir is set to until the gas reaches equilibrium at is positive, negative, or zero. With the block still on the piston, the thermal reservoir is changed to a new constant temperature . The gas is allowed to reach thermal equilibrium with the reservoir, and the piston comes to rest at a new final volume. The cylinder wall through which conduction occurs has thickness , thermal conductivity , and contact area with the gas . During the initial part of the heating, while the gas temperature is and the reservoir temperature is , assume the temperature difference across the wall is approximately constant.
given_values: ["M = 2.0 kg", "A = 5.0×10^-3 m^2", "P_atm = 1.00×10^5 Pa", "V0 = 1.50×10^-3 m^3", "T0 = 300 K", "m_b = 3.0 kg", "T_new = 360 K", "k = 15 W/(m·K)", "L = 2.0×10^-3 m", "A_w = 1.0×10^-2 m^2", "g = 9.8 m/s^2"]
Briefly justify your answer by referencing at least one microscopic interpretation (atomic motion and collisions) and one thermodynamic representation (such as your sketch from part C, the ideal gas model, or the direction of heat transfer by conduction).
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