2. A sample of a monatomic ideal gas is sealed in a vertical cylinder by a movable piston of mass and cross-sectional area . The piston moves with negligible friction. The pressure of the air above the piston is constant at . The cylinder is connected to a large thermal reservoir at temperature by a metal rod of length , cross-sectional area , and thermal conductivity . Initially the gas is in thermal equilibrium with the reservoir, the piston is at rest, and the gas occupies volume , as shown in Figure 1.
Figure 1. Monatomic ideal gas in a vertical cylinder sealed by a frictionless movable piston and thermally linked to a reservoir through a conducting rod (all given numerical values labeled).

Figure dot. Force diagram. Dot represents the piston (center of mass).

On the dot shown in Figure dot, representing the piston, draw and label the forces that are exerted on the piston. Each force must be represented by a distinct arrow starting on, and pointing away from, the dot.
Derive an expression for the internal energy of the gas in terms of , , , , and physical constants, as appropriate. Begin your derivation by writing a fundamental physics principle or an equation from the reference information.
Figure 2. Blank pressure–volume axes for sketching the gas process during t0 ≤ t ≤ tf.

On the axes provided in Figure 2, sketch the expected relationship between the pressure and volume of the gas for the thermodynamic process that the gas undergoes during the time interval . Draw an arrow on your sketch to represent the direction of the thermodynamic process. A metal block of mass is slowly placed on top of the piston at time . The piston moves downward and comes to rest at time with the gas in thermal equilibrium with the reservoir at temperature .
Indicate whether the entropy change of the gas during the interval is greater than, less than, or equal to zero. After the block remains on the piston, the thermal reservoir is changed to a new constant temperature while the gas is at volume . For a short time interval, the volume is held constant by a clamp, and energy is transferred only by conduction through the rod. Assume the temperature difference between the reservoir and the gas remains constant at during the interval of duration .
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Briefly justify your answer by referencing (i) the direction of energy transfer due to the temperature difference and (ii) at least one representation from your answers to parts A, B, or C.