1. A rigid, sealed, thermally insulated cylinder contains n=0.50mol of an ideal monatomic gas. The gas is initially in thermal equilibrium at temperature T1=300K and pressure P1=1.20×105Pa. A frictionless piston is then attached to the cylinder so that the gas can expand while remaining sealed. The piston is initially locked. The cross-sectional area of the piston is A=2.0×10−3m2. The cylinder is placed in thermal contact with a large thermal reservoir at temperature TR=450K by inserting a solid copper rod between the cylinder wall and the reservoir, as shown in Figure 1. The copper rod has length L=0.25m, cross-sectional area Arod=1.5×10−4m2, and thermal conductivity k=400W/(m·K). Heat transfer occurs only through the rod.
Figure 1. Thermally insulated gas cylinder with locked frictionless piston and heat transfer only through a copper rod to a 450 K reservoir.
Figure 2. Microscopic snapshot of gas particles at T1 = 300 K for drawing velocity vectors with different directions and speeds.
Figure 3. Single-particle collision with a wall segment showing the momentum-change direction normal to the wall.
A.
i.Complete the following tasks in Figures 2 and 3.
• Indicate in Figure 2 the directions of typical velocity vectors for several gas particles at T1=300K, and indicate which particles would be moving faster by drawing longer arrows.
• Indicate in Figure 3 the direction of the momentum change Δp of a particle during a collision with the wall segment shown, and explain briefly how many such collisions relate to the gas pressure.
ii.While the piston remains locked, the gas is warmed by the reservoir until it reaches T2=450K. Assume the volume remains constant during this heating.
Derive an expression for the final pressure P2 in terms of P1, T1, and T2. Begin your derivation by writing a fundamental physics principle or an equation from the reference information. Then calculate the numerical value of P2.
Figure 4. P–V diagram for the initial locked heating (constant volume) and the subsequent piston motion to a final resting state.
After the gas reaches T2=450K, the piston is unlocked. The outside of the piston is exposed to a constant atmospheric pressure Patm=1.00×105Pa. The piston has mass mp=6.0kg and remains frictionless. The gas stays in thermal contact with the reservoir through the rod, so during the piston motion the gas temperature is maintained at T=450K. Use g=9.8m/s2.
Given values:
n=0.50mol
T=450K
A=2.0×10−3m2
Patm=1.00×105Pa
mp=6.0kg
g=9.8m/s2
R=8.31J/(mol·K)
B.Indicate whether the process from the moment the piston is unlocked until the piston comes to rest is best modeled as isothermal, isobaric, or adiabatic (see Figure 4). ______ Isothermal ______ Isobaric ______ Adiabatic
Justify your answer.
Then calculate the final gas pressure Pf and the final gas volume Vf after the piston comes to rest.