Fiveable
🧲AP Physics 2
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🧲AP Physics 2

FRQ 1 – Mathematical Routines
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Unit 9: Thermodynamics
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Practice FRQ 1 of 121/12
1. A sealed cylinder contains n=0.500 moln = 0.500\ \text{mol}n=0.500 mol of a monatomic ideal gas and is fitted with a frictionless, movable piston of cross-sectional area A=4.00×10−3 m2A = 4.00× 10^{-3}\ \text{m}^2A=4.00×10−3 m2. The cylinder is initially in thermal equilibrium with a large reservoir at temperature T0=300 KT_0 = 300\ \text{K}T0​=300 K. The gas is initially at pressure P0=1.00×105 PaP_0 = 1.00× 10^5\ \text{Pa}P0​=1.00×105 Pa and volume V0V_0V0​. A schematic of the apparatus is shown in Figure 1.

Figure 1. Sealed cylinder with movable frictionless piston in thermal contact with an adjustable-temperature reservoir (initial state at T₀ and P₀).

A clean black-and-white physics apparatus schematic (no shading, no 3D perspective), centered on a tall vertical cylinder.

Overall layout (top to bottom):
- A vertical cylinder occupies the central half of the page width and most of the page height. The cylinder walls are two thick, straight, parallel vertical lines. The cylinder bottom is a thick horizontal line closing the container.
- A single movable piston is drawn as a thick horizontal rectangle that fits tightly inside the cylinder, spanning exactly between the inner faces of the two cylinder walls. The piston is located in the upper third of the cylinder height, leaving a large gas region beneath it.

Piston details:
- On the top face of the piston, draw a small label centered on the piston: "Frictionless movable piston".
- Next to the piston (on the right side of the piston, outside the cylinder), place the text label "Cross-sectional area A = 4.00 × 10⁻³ m²" with a short leader arrow pointing to the piston.

Gas region and state labels:
- The region inside the cylinder below the piston is labeled "monatomic ideal gas" in the center of that region.
- Inside the gas region, place three stacked lines of text centered horizontally:
  1) "n = 0.500 mol"
  2) "P₀ = 1.00 × 10⁵ Pa"
  3) "T₀ = 300 K"
- Near the lower half of the gas region (still inside the cylinder), place the volume label "V₀".

Thermal reservoir and contact:
- To the left of the cylinder, draw a large rectangular block representing a thermal reservoir. The block’s vertical span matches the middle half of the cylinder height, and its right face is separated from the cylinder’s left wall by a small gap.
- Between the reservoir block and the cylinder wall, draw a thin vertical contact region indicated by three short horizontal lines bridging the gap (suggesting thermal contact).
- Label the reservoir block "Thermal reservoir" centered inside the block.
- Above the reservoir block, place the label "Reservoir temperature adjustable".

Heat-flow notation:
- Draw a single horizontal arrow pointing from the reservoir toward the cylinder (left to right), positioned at the mid-height of the gas region.
- Label this arrow "Heat transfer (Q)" above the arrow.

Sealed condition cue:
- Above the piston (inside the cylinder’s top region), do NOT draw any gas region; instead, leave it blank and place the label "Sealed" near the top of the cylinder, indicating the container is closed and the piston moves without leakage.

All text must be exactly as written, including subscripts and scientific notation. No extra numbers or unlabeled forces.

Figure 2. Microscopic model of gas particles at state 0 (T₀) and state 1 (T₁) for comparing average speed and momentum transfer rate at the same volume.

A two-panel microscopic diagram with clear, rigid panel boundaries and identical box sizes.

Page layout:
- Two equal square panels are arranged side-by-side with a narrow gap between them.
- The left panel is labeled at its top-left corner: "(a) State 0" on the first line and "T₀ = 300 K" on the second line.
- The right panel is labeled at its top-left corner: "(b) State 1" on the first line and "T₁ = 450 K" on the second line.

Panel boundaries and ‘same volume’ constraint:
- Each panel is a perfect square container with thick black walls.
- The two squares must be the same size, visually enforcing that the volume is the same in (a) and (b).
- Add the text centered below both panels (spanning the full two-panel width): "Compare at the same volume (same box size)."

Particles:
- In EACH panel, draw exactly 10 identical particles as small filled circles.
- Particle circle size: each particle diameter is small, and all particles are identical in both panels.
- Particle placement rule: distribute particles across the interior so none touch the walls and none overlap; keep a similar spatial distribution in both panels (no clustering differences), so only speed-related markings differ.

Velocity depiction:
- In EACH panel, every particle has a straight arrow attached to it indicating its instantaneous velocity.
- All arrows originate at the center of each particle and extend outward.
- Panel (a): all velocity arrows are short and of comparable length.
- Panel (b): all velocity arrows are clearly longer than the arrows in panel (a), with the same variety of directions; the longest arrows in (b) must be at least twice the length of the arrows in (a).
- Do not include any numeric speeds.

Wall momentum-transfer reference:
- In EACH panel, highlight the RIGHT wall by making it slightly thicker than the other three walls.
- Place a label outside the right wall at mid-height: "Wall segment used for momentum-transfer comparison" with a leader line pointing to the right wall.

Student response prompts (must appear as printed text with blank lines):
- Directly beneath panel (b), place two stacked prompts with blank lines for student marks:
  1) "Average particle speed in (b) is: ______ greater  ______ less  ______ equal (compared to (a))"
  2) "At the same volume, average rate of momentum transfer to the wall in (b) is: ______ greater  ______ less  ______ equal (compared to (a))"

No other labels, equations, or numbers appear besides the panel labels, the ‘same volume’ line, the wall-segment label, and the two prompts.

Figure 3. Blank P–V diagram with states 0 and 1 at the same pressure P₀; students sketch the constant-pressure path from 0 to 1.

A blank pressure–volume graph intended for a process sketch.

Axes (all required markings shown):
- Horizontal axis label centered below the axis: "V (m³)".
- Vertical axis label rotated vertically along the left side: "P (Pa)".
- The axes intersect at the bottom-left corner and the intersection is labeled "0".
- Arrowheads appear on the positive end of the horizontal axis (pointing right) and on the positive end of the vertical axis (pointing up).

Numeric axis ranges and ticks:
- Horizontal axis (V): runs from 0 to 0.030. Tick marks every 0.005, with visible tick labels: 0, 0.005, 0.010, 0.015, 0.020, 0.025, 0.030.
- Vertical axis (P): runs from 0 to 2.00 × 10⁵. Tick marks every 0.50 × 10⁵, with visible tick labels: 0, 0.50 × 10⁵, 1.00 × 10⁵, 1.50 × 10⁵, 2.00 × 10⁵.
- No grid lines.

State points (must be plotted and labeled):
- State "0" is shown as a solid filled dot located at the tick level corresponding to "1.00 × 10⁵" on the pressure axis and at the tick corresponding to "0.0125" on the volume axis.
- Place the text label "0" slightly above and to the left of this dot.
- State "1" is shown as a solid filled dot at the SAME vertical height (same pressure as state 0) and at the volume tick corresponding to "0.01875".
- Place the text label "1" slightly above and to the right of this dot.

Instruction text on the graph:
- In the open space above the two points, print: "Sketch the process path from 0 to 1 (quasistatic, constant pressure P₀)."
- Next to the horizontal line level of the two points, place a small label near the left side: "P₀ = 1.00 × 10⁵ Pa".

Expected student sketch (what the blank provides guidance for):
- The figure itself includes NO pre-drawn process curve.
- The placement of points 0 and 1 at identical pressure visually constrains the student’s curve to be a horizontal line segment if they follow constant pressure.

Line styles:
- Axes are solid black, medium thickness.
- State dots are solid black.
- All text is black and unitalicized.
A.
i. The reservoir temperature is increased so that the gas reaches a new equilibrium temperature T1=450 KT_1 = 450\ \text{K}T1​=450 K while the piston is free to move.
Complete the following tasks in Figure 2.
• Indicate in Panel (b) whether the average speed of the particles is greater than, less than, or equal to that in Panel (a).
• Indicate in Panel (b) whether the average rate of momentum transfer to the cylinder wall (and thus the pressure) is greater than, less than, or equal to that in Panel (a) at the same volume.
ii. The gas is heated from T0T_0T0​ to T1T_1T1​ in a quasistatic process at constant pressure P0P_0P0​. Using Figure 3, sketch the process path from state 0 to state 1.
Derive an expression for the final volume V1V_1V1​ in terms of nnn, T1T_1T1​, and P0P_0P0​. Begin your derivation by writing a fundamental physics principle or an equation from the reference information.
B. Indicate whether the change in entropy of the gas is positive, negative, or zero.
______ Positive
______ Negative
______ Zero
Justify your answer.

Figure 4. Heat transfer through a metal plate of thickness L between a hot reservoir and the gas; plate area equals the cylinder cross-sectional area.

A vertical cylinder-and-reservoir conduction schematic, black-and-white, no perspective.

Overall layout (left to right):
- On the far left, draw a large vertical rectangular block labeled "Hot reservoir" centered inside the block.
- On the far right, draw the same vertical cylinder as in Figure 1 (two parallel vertical walls with a bottom line), with a movable piston near the top and gas beneath it.

Metal plate between reservoir and cylinder:
- Insert a thin vertical rectangular plate in the gap between the hot reservoir (left) and the cylinder wall (right), so the plate’s left face touches the reservoir’s right face and the plate’s right face touches the cylinder’s left wall.
- The plate’s vertical height matches the gas region height (it spans the same vertical range as the gas beneath the piston), indicating full contact.
- Label the plate "Metal plate" centered on it.

Thickness marking:
- Draw a double-headed horizontal dimension arrow across the plate thickness (from the plate’s left face to its right face), positioned at mid-height of the plate.
- Label this dimension arrow "L" directly above the arrow.

Area equality:
- Near the piston (right side of the figure), place the label "Cylinder cross-sectional area A = 4.00 × 10⁻³ m²" with a leader arrow pointing to the piston.
- Near the plate (center-left), place the label "Plate area A_plate = A" with a leader arrow pointing to the plate.

Heat-flow direction:
- Draw three parallel horizontal arrows pointing from the hot reservoir toward the cylinder (left to right), passing through the plate region.
- Above the arrows, place the label "Heat conducted into gas".

Gas label:
- Inside the cylinder below the piston, label the region "Gas".

No additional numbers besides A and the symbols A_plate and L. No equations. All labels are horizontal and clearly separated so none overlap the plate or arrows.






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