Classical vs quantum behavior refers to the contrasting ways in which physical systems operate at macroscopic scales compared to the microscopic, quantum scales. Classical behavior adheres to Newtonian mechanics and deterministic principles, while quantum behavior is characterized by probabilities, wave-particle duality, and phenomena like superposition and entanglement. Understanding these differences is crucial for grasping complex concepts such as quantum tunneling, where particles pass through potential barriers despite not having enough energy according to classical mechanics.