๐Ÿ’intro to chemistry review

Superoxides

Written by the Fiveable Content Team โ€ข Last updated September 2025
Written by the Fiveable Content Team โ€ข Last updated September 2025

Definition

Superoxides are compounds that contain the superoxide anion $O_2^-$. They are typically formed by alkali metals and some other metals.

5 Must Know Facts For Your Next Test

  1. The superoxide anion $O_2^-$ has an extra electron compared to the dioxygen molecule $O_2$.
  2. Potassium, rubidium, and cesium form stable superoxides due to their large atomic radii.
  3. Superoxides are strong oxidizing agents and can react violently with water or acids.
  4. In a superoxide, the oxidation state of oxygen is -1/2.
  5. Superoxides play a role in biological systems as reactive oxygen species (ROS), which can cause oxidative stress.

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