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P_total

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Intro to Chemistry

Definition

P_total, or total pressure, is the sum of the partial pressures of all the gases present in a mixture. It represents the overall pressure exerted by a gaseous mixture and is a fundamental concept in the stoichiometry of gaseous substances, mixtures, and reactions.

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5 Must Know Facts For Your Next Test

  1. P_total is the sum of the partial pressures of all the gases present in a gaseous mixture.
  2. Partial pressure is the pressure exerted by a specific gas in a mixture, independent of the presence of other gases.
  3. Dalton's Law of Partial Pressures states that the total pressure of a gas mixture is equal to the sum of the partial pressures of the individual gases.
  4. Mole fraction is the ratio of the number of moles of a particular gas to the total number of moles in a mixture, and is used to calculate partial pressures.
  5. P_total is an essential parameter in the stoichiometric calculations of gaseous reactions, as it allows for the determination of the quantities of reactants and products involved.

Review Questions

  • Explain how P_total is calculated based on the partial pressures of the individual gases in a mixture.
    • P_total is calculated by summing the partial pressures of all the gases present in a mixture. The partial pressure of each gas is determined by its mole fraction in the mixture, according to Dalton's Law of Partial Pressures. Specifically, the partial pressure of a gas is equal to its mole fraction multiplied by the total pressure of the mixture. By adding up the partial pressures of all the individual gases, you can determine the P_total, which represents the overall pressure exerted by the gaseous mixture.
  • Describe the relationship between P_total and the stoichiometry of gaseous reactions.
    • P_total is a crucial parameter in the stoichiometric calculations of gaseous reactions. The total pressure of the system affects the quantities of reactants and products involved in the reaction, as well as the equilibrium conditions. Knowing the P_total allows you to determine the partial pressures of the reactants and products, which is necessary to calculate the amounts of substances participating in the reaction. Additionally, changes in P_total can shift the equilibrium of a reaction, as described by Le Chatelier's principle, which is important for understanding the stoichiometry of gaseous mixtures and reactions.
  • Analyze how the mole fraction of a gas in a mixture influences its partial pressure and the overall P_total.
    • The mole fraction of a gas in a mixture is directly proportional to its partial pressure, according to Dalton's Law of Partial Pressures. As the mole fraction of a gas increases, its partial pressure also increases, contributing more to the overall P_total. Conversely, if the mole fraction of a gas decreases, its partial pressure will also decrease, resulting in a lower contribution to the P_total. This relationship between mole fraction, partial pressure, and P_total is essential for understanding the stoichiometry of gaseous mixtures and reactions, as the relative quantities of the gases present in the system will determine the partial pressures and the overall P_total, which in turn affects the reaction kinetics and equilibrium.

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