13.2 Thermal Expansion of Solids and Liquids

3 min readjune 18, 2024

Temperature changes cause materials to expand or contract, affecting their dimensions and properties. This phenomenon, known as , is crucial in engineering and everyday life, from designing bridges to creating thermometers.

Thermal expansion occurs because increased temperature boosts atomic , causing particles to move more vigorously. This leads to greater average separation between particles, resulting in overall expansion. Different materials expand at varying rates, influencing their behavior under temperature changes.

Thermal Expansion

Thermal expansion effects

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  • Matter changes dimensions when temperature changes
    • Solids expand when heated and contract when cooled ()
    • Liquids expand when heated and contract when cooled ()
  • Increased temperature leads to increased average kinetic energy of atoms or molecules
    • Particles move more vigorously, maintaining greater average separation, causing expansion (vibrating atoms in a )
  • Degree of expansion varies based on material properties
    • Different materials have different coefficients of thermal expansion (aluminum vs. glass)
  • Thermal expansion causes changes in dimensions, volume, and
    • Linear expansion affects length (metal rod)
    • affects surface area (metal sheet)
    • Volume expansion affects volume (water in a tank)
  • Thermal expansion can lead to changes in density as the mass remains constant while volume changes

Linear expansion calculations

  • Calculate linear expansion using: ΔL=αL0ΔT\Delta L = \alpha L_0 \Delta T
    • ΔL\Delta L = change in length
    • α\alpha = , a material property (K1\text{K}^{-1} or C1^\circ\text{C}^{-1})
    • L0L_0 = initial length
    • ΔT\Delta T = change in temperature
  • measures expansion per unit length per degree of temperature change
    • Example: α=2×105K1\alpha = 2 \times 10^{-5} \text{K}^{-1} for steel
  • Calculate new length after thermal expansion: Lf=L0+ΔLL_f = L_0 + \Delta L
    • LfL_f = final length after expansion
    • Example: Lf=1m+(2×105K1)(1m)(10K)=1.0002mL_f = 1 \text{m} + (2 \times 10^{-5} \text{K}^{-1})(1 \text{m})(10 \text{K}) = 1.0002 \text{m}

Volume expansion determination

  • Calculate volume expansion using: ΔV=βV0ΔT\Delta V = \beta V_0 \Delta T
    • ΔV\Delta V = change in volume
    • β\beta = , a material property
    • V0V_0 = initial volume
    • ΔT\Delta T = change in temperature
  • Coefficient of volume expansion is approximately three times coefficient of linear expansion for most materials: β3α\beta \approx 3\alpha
    • Example: β3(2×105K1)=6×105K1\beta \approx 3(2 \times 10^{-5} \text{K}^{-1}) = 6 \times 10^{-5} \text{K}^{-1} for steel
  • Calculate new volume after thermal expansion: Vf=V0+ΔVV_f = V_0 + \Delta V
    • VfV_f = final volume after expansion
    • Example: Vf=1m3+(6×105K1)(1m3)(10K)=1.0006m3V_f = 1 \text{m}^3 + (6 \times 10^{-5} \text{K}^{-1})(1 \text{m}^3)(10 \text{K}) = 1.0006 \text{m}^3

Thermal stress analysis

  • occurs when an object is constrained while undergoing thermal expansion or contraction
    • Constraint prevents free expansion or contraction, leading to internal stresses (railroad tracks buckling on a hot day)
  • can cause deformation, buckling, or breakage if stress exceeds material's strength
    • Example: glass shattering when subjected to rapid temperature change
  • Magnitude of thermal stress depends on material properties
    • Coefficient of thermal expansion
    • (measure of material's stiffness)
  • Calculate thermal stress using: σ=[E](https://www.fiveableKeyTerm:E)αΔT\sigma = [E](https://www.fiveableKeyTerm:E)\alpha\Delta T
    • σ\sigma = thermal stress
    • EE = elastic modulus
    • α\alpha = coefficient of linear expansion
    • ΔT\Delta T = change in temperature
  • Minimize thermal stress by:
    1. Using materials with similar coefficients of thermal expansion in applications with expected temperature changes ( in a thermostat)
    2. Allowing for expansion joints or gaps to reduce thermal stress in structures (bridge expansion joints)

Thermal Equilibrium and Energy Transfer

  • occurs when two objects reach the same temperature through heat transfer
  • The process of reaching involves the transfer of kinetic energy between particles
  • As objects expand or contract due to temperature changes, they work towards achieving thermal equilibrium with their surroundings

Key Terms to Review (33)

°C⁻¹: °C⁻¹ is a unit of measurement that represents the reciprocal of the Celsius temperature scale, indicating the change in temperature per unit of another quantity, such as time or distance. This term is particularly relevant in the context of thermal expansion of solids and liquids.
Area Expansion: Area expansion is the increase in the surface area of a material or object due to thermal effects. It is a consequence of the thermal expansion that occurs when a substance is heated, causing its molecules to vibrate more and occupy a greater volume.
Bimetallic Strip: A bimetallic strip is a device composed of two different metals bonded together. The differing thermal expansion coefficients of the two metals cause the strip to bend or curve when exposed to changes in temperature, making it a useful tool for temperature measurement and control applications.
Coefficient of linear expansion: The coefficient of linear expansion is a material property that quantifies the rate at which a material's length changes with temperature. It is typically denoted by the Greek letter $\alpha$ and has units of inverse temperature (e.g., $\text{°C}^{-1}$ or $\text{K}^{-1}$).
Coefficient of Linear Expansion: The coefficient of linear expansion is a measure of the fractional change in length of a material per unit change in temperature. It quantifies the thermal expansion of solids and liquids, describing how their linear dimensions change with temperature.
Coefficient of volume expansion: The coefficient of volume expansion is a material-specific constant that quantifies the change in volume of a substance per unit change in temperature. It is typically denoted by $\beta$ and has units of $\text{K}^{-1}$.
Critical density: Critical density is the theoretical density of matter needed for the universe to have a flat geometry. It determines whether the universe will expand forever, collapse back on itself, or reach a stable size.
Crystal Lattice: A crystal lattice is the regular, repeating, three-dimensional pattern in which atoms or molecules are arranged in a crystalline solid. This orderly arrangement is a fundamental characteristic of crystalline materials and is crucial in understanding the thermal expansion properties of solids and liquids.
Density: Density is a fundamental physical property that describes the mass per unit volume of a substance. It is a crucial concept in understanding the behavior of fluids and the principles governing various physical phenomena related to pressure, buoyancy, and fluid flow.
Dilatometer: A dilatometer is an instrument used to measure the thermal expansion or contraction of materials, particularly solids and liquids, as a function of temperature. It is a crucial tool in the study of thermal expansion, a key concept in the topics of 13.2 Thermal Expansion of Solids and Liquids.
E: In physics, 'E' commonly represents energy, which is the capacity to do work or produce change. Energy can take various forms, such as thermal, kinetic, potential, or electrical, and is a fundamental concept that connects diverse phenomena in the physical world. Understanding energy helps explain processes such as heat transfer in materials, the intensity of waves, and the behavior of electric fields around charged particles.
Elastic Modulus: The elastic modulus, also known as Young's modulus, is a measure of the stiffness of a solid material. It quantifies the relationship between the stress applied to a material and the resulting strain, providing insight into a material's ability to withstand deformation under load.
Internal kinetic energy: Internal kinetic energy is the sum of the kinetic energies of all particles within a system. It plays a crucial role in understanding how energy is distributed and conserved during elastic collisions.
K⁻¹: K⁻¹ is the inverse of the thermal expansion coefficient, K, which is a measure of the relative change in the size or volume of a material in response to a change in temperature. The inverse of the thermal expansion coefficient, K⁻¹, represents the resistance of a material to thermal expansion and is an important parameter in understanding the behavior of solids and liquids under thermal stress.
Kinetic Energy: Kinetic energy is the energy of motion possessed by an object. It is the energy an object has by virtue of being in motion and is directly proportional to the mass of the object and the square of its velocity. Kinetic energy is a crucial concept in physics, as it relates to the work done on an object, the conservation of energy, and various other physical phenomena.
L₀: L₀ is the initial or reference length of a material before any changes in temperature are applied. It is a crucial parameter in the study of thermal expansion, as it serves as the baseline for calculating the amount of expansion or contraction experienced by a solid or liquid material when subjected to changes in temperature.
Lf: Lf, or linear factor, is a term used to describe the relationship between the change in length of a material and the change in temperature. It is a crucial concept in understanding the thermal expansion of solids and liquids.
Mercury Thermometer: A mercury thermometer is a type of temperature-measuring device that uses the thermal expansion of mercury to indicate the temperature. It is a commonly used tool for measuring the temperature of solids, liquids, and gases, particularly in the context of thermal expansion.
Railroad Tracks: Railroad tracks are the parallel steel rails that guide and support the wheels of trains as they move along a railway. These tracks are a critical component of the transportation infrastructure, enabling the efficient and reliable movement of goods and people across vast distances.
Thermal equilibrium: Thermal equilibrium is the state in which two or more objects in contact do not exchange heat, meaning they are at the same temperature. No net heat flow occurs between them.
Thermal Equilibrium: Thermal equilibrium is a state where two or more objects or systems have the same temperature and no net heat transfer occurs between them. This concept is fundamental in understanding the behavior of temperature, heat, and thermodynamics.
Thermal expansion: Thermal expansion is the increase in volume of a substance due to an increase in temperature. This occurs because particles move more and take up more space as they absorb heat.
Thermal stress: Thermal stress is the stress created in a material when it undergoes changes in temperature, leading to expansion or contraction. It occurs because different parts of the material may expand or contract at different rates.
Thermal Stress: Thermal stress refers to the internal forces and deformations experienced by a material or structure due to changes in temperature. It arises from the tendency of materials to expand or contract when heated or cooled, respectively, which can lead to the development of stresses and strains within the system.
V₀: V₀ is a fundamental variable used in the study of thermal expansion, representing the initial or reference volume of a material before it undergoes a change in temperature. This term is crucial in understanding how the volume of solids and liquids changes as a result of temperature variations.
Vf: Vf, or final velocity, is a fundamental concept in the study of thermal expansion of solids and liquids. It represents the velocity or speed of an object or system after it has undergone a change in temperature, which can lead to a change in its physical dimensions.
Volumetric Expansion: Volumetric expansion is the increase in the volume of a substance, typically a solid or liquid, due to an increase in temperature. This phenomenon is observed in both solids and liquids and is an important concept in the study of thermal physics.
α: α, or alpha, is a variable used to represent various physical quantities in different contexts. In the fields of rotational dynamics and thermal expansion, α holds specific meanings and plays important roles in understanding the underlying principles.
β (Beta): β (beta) is a dimensionless quantity that represents the coefficient of thermal expansion for solids and liquids. It is a measure of the fractional change in volume or length of a material per unit change in temperature, and is a fundamental property that describes the thermal expansion behavior of a substance.
ΔL: ΔL represents the change in length of an object due to thermal expansion or contraction. It is a fundamental concept in understanding the effects of temperature changes on the dimensions of solids and liquids.
Δt: Δt represents the change in time, which is a crucial concept in understanding motion and physical processes. This term highlights the difference between two specific time points, enabling the calculation of rates such as speed and velocity. It also plays a vital role in analyzing thermal processes and energy transfer by showing how time intervals affect the behavior of materials and systems.
ΔV: ΔV, or change in volume, is a fundamental concept in physics that describes the difference in volume between two states or conditions of a system. This term is particularly relevant in the context of thermal expansion of solids and liquids, as well as the first law of thermodynamics and its associated processes.
σ (Sigma): Sigma (σ) is a Greek letter commonly used in physics and mathematics to represent various physical quantities, particularly those related to stress and strain. In the context of thermal expansion of solids and liquids, sigma is a crucial parameter that describes the material's response to changes in temperature. Sigma is a fundamental concept in the study of thermal expansion, as it quantifies the degree to which a material expands or contracts when subjected to temperature variations. This property is essential in understanding the behavior of materials under different thermal conditions, which is crucial for engineering applications, such as the design of structures, mechanical systems, and electronic devices.
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