1.4 Measurements

3 min readjune 24, 2024

Scientific is the backbone of chemistry. It's how we quantify and communicate our findings. By using standard and methods, we ensure our results are consistent and verifiable.

Measuring involves more than just numbers. It's about capturing the essence of physical properties like , mass, and volume. Understanding units, , and helps us interpret data and draw meaningful conclusions.

Measurement Fundamentals

Fundamentals of scientific measurement

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  • Quantifying physical properties using standard units enables consistent communication of findings
  • Comparing measured quantities to known standards allows for reproducibility and verification
  • Measurement process involves identifying the property (length), selecting an appropriate instrument (ruler), comparing to the standard unit, and recording the numerical value with the unit

Components of measured quantities

  • Numerical value represents the number obtained from the measurement (5.2)
  • Unit is the standard quantity used for comparison (meters)
    • Provides context and meaning to the numerical value
  • indicates the range within which the true value is expected (± 0.1 meters)
    • Arises from limitations in the instrument (ruler ) and measurement process (human error)
    • Expressed using (5.2 m) or error bars in graphs

Measurement Quality

  • refers to how close a measurement is to the true value
  • Precision describes the reproducibility of measurements and their closeness to each other
  • Both accuracy and precision are important for reliable scientific measurements

Physical Properties and Units

Key physical properties

  • Length measures distance between two points (height of a building)
    • Common units include meters (m), centimeters (cm), and inches (in)
  • Mass quantifies the amount of matter in an object (weight of a textbook)
    • Measured in grams (g) or kilograms (kg)
    • Distinct from weight, which is the gravitational force on an object
  • Volume is the amount of space occupied by an object (capacity of a water bottle)
    • Expressed in liters (L), milliliters (mL), or cubic meters (m3m^3)
  • relates an object's mass to its volume ([density](https://www.fiveableKeyTerm:Density)=massvolume[density](https://www.fiveableKeyTerm:Density) = \frac{mass}{volume})
    • Allows for comparison of substances (water vs. oil)
    • Common units include grams per (g/mLg/mL) and kilograms per cubic (kg/m3kg/m^3)
  • Temperature measures the average kinetic energy of particles in a substance (air temperature)
    • Scales include , , and (°F)
  • Time is the duration between two events (length of a lecture)
    • Measured in seconds (s), minutes (min), and hours (h)

Unit conversions and calculations

  • is a decimal-based system commonly used in science
    • Prefixes indicate magnitude (kilometer = 1000 meters)
    • Base units include meters (m) for length, grams (g) for mass, and liters (L) for volume
  • Other systems include U.S. customary units (inches, pounds) and imperial units (miles, stones)
  • The (SI) is the modern form of the metric system used globally in science
  • Unit conversions change a quantity from one unit to another
    • Multiply or divide by conversion factors (1 in = 2.54 cm)
    • Example: Converting 5 cm to meters 5cm×0.01m1cm=0.05m5 cm \times \frac{0.01 m}{1 cm} = 0.05 m
  • is a problem-solving method for conversions and calculations
    1. Identify the given quantity and desired unit (5 cm to m)
    2. Set up a series of fractions with conversion factors (5cm1×0.01m1cm\frac{5 cm}{1} \times \frac{0.01 m}{1 cm})
    3. Cancel out units until only the desired unit remains (5  cm  1×0.01m1  cm  =0.05m\frac{5 ~~cm~~}{1} \times \frac{0.01 m}{1 ~~cm~~} = 0.05 m)
  • is used to express very large or very small numbers in a compact form (e.g., 6.022 × 10²³)

Key Terms to Review (37)

Accuracy: Accuracy refers to how close a measured value is to the true or accepted value. It indicates the correctness of a measurement.
Accuracy: Accuracy is the closeness of a measured value to the true or accepted value of the quantity being measured. It is a key concept in the context of measurements, measurement uncertainty, and the mathematical treatment of measurement results.
Celsius: Celsius is a temperature scale used to measure how hot or cold an object or environment is, defined such that 0 degrees Celsius (°C) represents the freezing point of water and 100 degrees Celsius represents the boiling point at standard atmospheric pressure. This scale is commonly used in scientific contexts due to its relation to the physical properties of water, making it easy to understand temperature changes in everyday life.
Celsius (°C): Celsius (°C) is a temperature scale used in the metric system where 0°C is the freezing point of water and 100°C is the boiling point at standard atmospheric pressure. It is commonly used in scientific contexts and everyday life outside the United States.
Centimeter: A centimeter is a unit of length in the metric system, equal to one-hundredth of a meter. It is a commonly used unit for measuring small distances and is particularly useful in the context of scientific measurements and everyday applications.
Cubic centimeter (cm3): A cubic centimeter (cm³) is a unit of volume in the metric system. It represents the volume of a cube with sides that are each one centimeter in length.
Cubic meter (m3): A cubic meter (m^3) is a unit of volume in the International System of Units (SI). It represents the volume of a cube with each side measuring one meter.
Density: Density is a measure of mass per unit volume. It is typically expressed in units such as grams per cubic centimeter (g/cm³) or kilograms per cubic meter (kg/m³).
Density: Density is a physical property that describes the mass per unit volume of a substance. It is a fundamental concept in chemistry and physics that helps characterize the structure and composition of materials.
Dimensional analysis: Dimensional analysis is a mathematical technique used to convert one set of units to another. It involves multiplying by conversion factors that express the same quantity in different units.
Dimensional Analysis: Dimensional analysis is the process of analyzing and manipulating the dimensions of physical quantities to verify the dimensional consistency of equations, convert between different units, and solve problems involving multiple measurements. It is a powerful tool used in various scientific and engineering fields to ensure the validity and accuracy of calculations and relationships between physical quantities.
Fahrenheit: Fahrenheit is a temperature scale that measures the degree of hotness or coldness of an object or substance. It is commonly used in the United States and a few other countries, with the freezing point of water being 32°F and the boiling point of water being 212°F at standard atmospheric pressure.
Gram: The gram is a unit of measurement used to quantify mass or weight. It is a fundamental unit in the metric system and serves as the base unit for measuring the mass of substances in chemistry and other scientific fields.
Heisenberg uncertainty principle: The Heisenberg uncertainty principle states that it is impossible to simultaneously know the exact position and momentum of a particle. This principle is fundamental in quantum mechanics and highlights the limitations of measuring certain pairs of complementary properties.
Inch: The inch is a commonly used unit of length in the imperial measurement system. It is a small unit of measurement that is often used to describe the dimensions of objects and spaces in everyday life.
International System of Units: The International System of Units (SI) is the modern standardized metric system of measurement used worldwide. It is the internationally recognized system of units that defines measures for various physical quantities, such as length, mass, time, temperature, and more.
Kelvin: Kelvin is the base unit of temperature in the International System of Units (SI). It is named after the physicist William Thomson, also known as Lord Kelvin, who was the first to propose an absolute scale of temperature. The Kelvin scale is a fundamental quantity in various areas of chemistry, including measurements, the ideal gas law, collision theory, and the study of spontaneity.
Kelvin (K): Kelvin (K) is the SI unit of thermodynamic temperature. It is one of the seven base units in the International System of Units (SI).
Kilogram: The kilogram is the base unit of mass in the International System of Units (SI). It is the primary unit used to measure the amount of matter in an object and is a fundamental quantity in the study of chemistry and physics.
Kilogram (kg): A kilogram (kg) is the base unit of mass in the International System of Units (SI). It is defined by the mass of the International Prototype of the Kilogram, a platinum-iridium cylinder stored in France.
Length: Length is a measurement of the extent of an object or distance from one point to another in one dimension. It is typically measured in units such as meters (m), centimeters (cm), or inches (in).
Liter: A liter is a unit of volume in the metric system that is commonly used to measure the capacity of containers, such as bottles, cans, and jugs. It is a fundamental unit of measurement in the context of 1.4 Measurements, as it provides a standardized way to quantify and compare volumes of various substances.
Liter (L): A liter (L) is a unit of volume in the metric system. It is commonly used to measure liquids.
Measurement: Measurement is the process of quantifying the attributes or dimensions of an object or phenomenon. It involves the use of standardized units and techniques to determine the size, amount, or degree of something with precision and accuracy.
Meter: A meter is a fundamental unit of length in the International System of Units (SI), used to measure distance and dimensions. It serves as the primary unit for quantifying and comparing physical quantities related to length, width, height, and other spatial measurements.
Meter (m): A meter (m) is the base unit of length in the International System of Units (SI). It is defined as the distance light travels in a vacuum in 1/299,792,458 seconds.
Metric System: The metric system is a decimal-based system of measurement used internationally to measure various quantities, including length, mass, volume, and temperature. It is the predominant measurement system used in science, medicine, and many other fields worldwide.
Milliliter: A milliliter (mL) is a unit of volume in the metric system, representing one-thousandth of a liter. It is commonly used to measure small volumes of liquids and is an essential unit in the context of chemical measurements and laboratory procedures.
Milliliter (mL): A milliliter (mL) is a unit of volume in the metric system, equal to one-thousandth of a liter. It is commonly used to measure small amounts of liquids.
Precision: Precision refers to the consistency of a set of measurements or results. It indicates how close the measurements are to each other, regardless of their accuracy.
Precision: Precision refers to the degree of closeness or reproducibility of a measurement. It is a measure of how consistently a measurement can be repeated, regardless of its accuracy in relation to the true value.
Scientific Notation: Scientific notation is a compact way of expressing very large or very small numbers by representing them as a product of a number between 1 and 10 multiplied by a power of 10. This method is particularly useful for calculations and data representation in the context of scientific measurements and mathematical treatment of measurement results.
Second (s): The second (s) is the base unit of time in the International System of Units (SI). It is defined by taking the fixed numerical value of the cesium-133 atom's ground-state hyperfine transition frequency.
Significant figures: Significant figures are the digits in a measurement that carry meaningful information about its precision. They include all certain digits plus one uncertain or estimated digit.
Significant Figures: Significant figures, also known as significant digits, are the meaningful numbers in a measurement or calculation that indicate the precision of the value. They represent the number of digits that are known with certainty, including the uncertain last digit. Significant figures are crucial in the context of measurements, measurement uncertainty, accuracy, and precision, as well as the mathematical treatment of measurement results.
Uncertainty: Uncertainty is the degree of imprecision or lack of exact knowledge in a measurement or observation. It reflects the inherent variability or unpredictability associated with a quantity or process, and is a fundamental concept in the context of scientific measurements and data analysis.
Units: Units are standardized quantities used to specify measurements. They provide a reference for expressing physical quantities consistently.
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