--- title: "Face-Centered Cubic (FCC) Solid | Intro to Chemistry" description: "Face-centered cubic (FCC) solid is a crystal structure with atoms at cube corners and face centers, giving high packing efficiency in Intro to Chemistry." canonical: "https://fiveable.me/intro-chem/key-terms/face-centered-cubic-fcc-solid" type: "key-term" subject: "Intro to Chemistry" unit: "Unit 10" --- # Face-Centered Cubic (FCC) Solid | Intro to Chemistry ## Definition A face-centered cubic (FCC) solid is a crystalline structure in which atoms sit at each corner and the center of each face of a cube. In Intro to Chemistry, it shows up when you study unit cells, density, and packing efficiency. ## What It Is A face-centered cubic (FCC) solid is a crystal structure in Intro to Chemistry where atoms occupy all eight corners of a cube and the center of each of the six faces. That arrangement makes the unit cell one of the most tightly packed ways atoms can organize in a solid. The corners and face centers are not counted the same way. Each corner atom belongs to eight neighboring unit cells, so each corner contributes 1/8 to one unit cell. Each face-centered atom is shared by two unit cells, so each face contributes 1/2. When you add those up, an FCC unit cell contains 4 atoms total. What makes FCC stand out is how the atoms touch. In this structure, each atom has a coordination number of 12, meaning it is touching 12 nearest neighbors. That high contact number is part of why FCC solids are dense and stable in many metals. FCC is also known for a high atomic packing factor, or APF, of 0.74. That means about 74% of the unit cell volume is occupied by atoms, with the rest being empty space. For comparison, some other crystal structures leave more open space, so FCC is one of the most efficient ways to pack spheres in three dimensions. In Intro to Chemistry, you usually meet FCC when looking at metallic solids like aluminum, copper, gold, and silver. These examples matter because the structure helps explain physical properties such as density, malleability, and how atoms repeat in a crystal lattice. If you can picture the cube with corner and face atoms, you can usually identify an FCC solid in diagrams and use the structure to count atoms or compare packing. ## Why It Matters FCC shows up whenever Intro to Chemistry connects structure to properties. A metal is not just a pile of atoms, it has a repeating arrangement, and FCC is one of the main ways metals can organize. That arrangement helps explain why some metals are compact, why they have high densities, and why their atoms fit together with very little wasted space. It also gives you a clean way to move from a picture to a calculation. If you know the unit cell is FCC, you can count atoms per unit cell, use the coordination number, and connect the structure to the atomic packing factor. Those are the kinds of steps that show up in problem sets on solids and crystal lattices. FCC is also a good comparison point. When you put it next to body-centered cubic or hexagonal close-packed structures, you start seeing how different arrangements can change packing, density, and neighbor contact even when the atoms are the same element. That is a big theme in solid-state chemistry: structure shapes properties. ## Connections ### [Coordination Number](/intro-chem/key-terms/coordination-number) FCC has a coordination number of 12, which means each atom touches 12 nearest neighbors. That number is a fast clue that the structure is tightly packed. When you see a crystal diagram, counting nearest neighbors helps you connect the visual model to the structure name and to properties like density and stability. ### Atomic Packing Factor (APF) The APF for FCC is 0.74, so it is one of the most efficient ways to pack atoms in a crystal. In problem sets, APF helps you compare FCC to other lattices and explain why some solids have less empty space. It is a direct measure of how tightly the atoms fill the unit cell. ### Body-Centered Cubic (BCC) BCC is the most common comparison for FCC because both are cubic unit cells, but they pack differently. BCC has one atom in the center of the cube and lower packing efficiency than FCC. If you can tell them apart in a diagram, you can usually answer structure, density, and counting questions more confidently. ### [Hexagonal Close-Packed](/intro-chem/key-terms/hexagonal-close-packed) Hexagonal close-packed, or HCP, is another tightly packed structure, and it is often paired with FCC in solid-state chemistry. Both are close-packed, but the layer arrangement is different. Comparing FCC and HCP helps you see that the same type of dense packing can happen in more than one geometric pattern. ## On the AP Exam A quiz question might show you a cube diagram and ask you to identify the lattice type, count atoms per unit cell, or find the coordination number. For FCC, you should recognize the atoms at all eight corners and all six face centers, then use the sharing rules to get 4 atoms total. In problem sets, FCC often appears in density or packing questions. You may be asked to compare FCC with BCC, explain why a metal has a high packing factor, or interpret why a crystal is dense. On a lab or model-building activity, you might classify a metal structure from a diagram or from a ball-and-stick crystal model. The move is usually the same: spot the geometry first, then use it to infer properties. ## face-centered cubic (FCC) solid vs Body-Centered Cubic (BCC) FCC and BCC are both cubic crystal structures, so they are easy to mix up at first. The difference is where the atoms sit and how tightly they pack. FCC has atoms at face centers and a coordination number of 12, while BCC has one atom in the center of the cube and fewer nearest neighbors. ## Key Takeaways - A face-centered cubic (FCC) solid has atoms at the corners and face centers of a cube. - An FCC unit cell contains 4 atoms total when you count shared corner and face atoms correctly. - FCC has a coordination number of 12, so each atom touches 12 nearest neighbors. - The atomic packing factor for FCC is 0.74, which means it is very densely packed. - Common FCC metals include aluminum, copper, gold, and silver. ## FAQs ### What is a face-centered cubic (FCC) solid in Intro to Chemistry? It is a crystal structure where atoms sit at each cube corner and at the center of each face. In Intro to Chemistry, FCC is one of the main unit-cell patterns you use to study crystal lattices, density, and packing efficiency. ### How many atoms are in an FCC unit cell? An FCC unit cell contains 4 atoms total. The eight corner atoms contribute 1 atom altogether, and the six face-centered atoms contribute 3 atoms altogether, because each one is shared between two unit cells. ### What is the difference between FCC and BCC? FCC has atoms at the face centers, while BCC has one atom in the center of the cube. FCC is more tightly packed, with a coordination number of 12 and a higher atomic packing factor than BCC. ### Why are metals like copper and aluminum FCC? Their atoms settle into a close-packed arrangement that is energetically favorable for the solid. That structure gives them high packing efficiency, which helps explain their density and some of their mechanical properties. ## Related Study Guides - [10.6 Lattice Structures in Crystalline Solids](/intro-chem/unit-10/6-lattice-structures-crystalline-solids/study-guide/WBLIxs7alTEzKMhh) - [10.5 The Solid State of Matter](/intro-chem/unit-10/5-solid-state-matter/study-guide/ma8N2iwhbE0Ekxai) ## About This Document Canonical Fiveable pages are available as Markdown at the same path plus `.md`. - [llms.txt](https://fiveable.me/llms.txt): index of Fiveable's sections and URL patterns - [llms-full.txt](https://fiveable.me/llms-full.txt): complete subject and unit listing - [MCP server](https://fiveable.me/mcp): call Fiveable as tools instead of fetching pages (`https://fiveable.me/api/mcp`) - [MCP server for AP teachers](https://fiveable.me/mcp/teachers): a teacher's classes, assignments and AP-rubric grading (`https://fiveable.me/api/mcp/teacher`) ## Structured Data ```json {"@context":"https://schema.org","@graph":[{"@type":"LearningResource","@id":"https://fiveable.me/intro-chem/key-terms/face-centered-cubic-fcc-solid#resource","name":"Face-Centered Cubic (FCC) Solid | Intro to Chemistry","url":"https://fiveable.me/intro-chem/key-terms/face-centered-cubic-fcc-solid","learningResourceType":"Concept explainer","educationalLevel":"AP® / High School","about":{"@id":"https://fiveable.me/intro-chem/key-terms/face-centered-cubic-fcc-solid#term"},"audience":{"@type":"EducationalAudience","educationalRole":"student"},"dateModified":"2026-07-03T02:22:18.202Z","isPartOf":{"@type":"Collection","name":"Intro to Chemistry Key Terms","url":"https://fiveable.me/intro-chem/key-terms"},"author":{"@type":"Organization","@id":"https://fiveable.me/editorial#content-team","name":"Fiveable Content Team","url":"https://fiveable.me/editorial","parentOrganization":{"@id":"https://fiveable.me/#organization"},"member":[{"@type":"Person","name":"Amanda DoAmaral","sameAs":["https://www.linkedin.com/in/adoamaral"]},{"@type":"Person","name":"Becky Bahr","sameAs":["https://www.linkedin.com/in/becky-bahr-b52743132"]}]},"publisher":{"@type":"Organization","name":"Fiveable","url":"https://fiveable.me"}},{"@type":"DefinedTerm","@id":"https://fiveable.me/intro-chem/key-terms/face-centered-cubic-fcc-solid#term","name":"face-centered cubic (FCC) solid","description":"A face-centered cubic (FCC) solid is a crystalline structure in which atoms sit at each corner and the center of each face of a cube. 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